高级检索

    锂离子电池健康状态估计的特征提取:方法与应用

    Feature Extraction for Lithium-Ion Battery State of Health Estimation: Methods and Applications

    • 摘要: 为了确保锂离子电池系统的安全性、可靠性和持久性,准确估计电池的健康状态(State of Health, SOH)至关重要。SOH作为一个内部状态量,难以通过传感器直接测量,往往需要通过间接方式进行估计。SOH估计的准确性在很大程度上依赖于健康特征的提取质量,当前SOH估计研究面临电池内部复杂的电化学衰退机制难以直接观测,且单一特征往往无法全面捕捉电池老化过程的挑战。首先阐明了SOH与电池容量衰减、内阻增长的宏观联系,并追溯其活性物质损失(LAM)和活性锂损失(LLI)等微观电化学衰减机制,确立了理想健康特征应具备明确物理意义的评价基准。在此基础上,总结了当前主流的特征提取技术,主要包括基于电压电流曲线、微分曲线、脉冲功率特性、电化学阻抗和多物理场的特征提取,并对这5种特征提取技术进行了归纳与评述。此外,系统梳理了NASA、CALCE、Oxford等多个国际公认的锂电池公开数据集,为相关算法的开发与验证提供了基准。最后,针对单一特征难以在复杂多变的工况下实现鲁棒性、高精度SOH估计的现状,提出未来发展趋势的三个关键方向:(1)建立标准化的评估协议,实现客观的算法比较;(2)融合多物理场特征(电、热、机械等),创建更全面、更稳健的健康指标;(3)将物理模型与数据驱动方法相结合(如物理信息神经网络),提高模型可解释性、数据效率和泛化能力。

       

      Abstract: To ensure the safety, reliability and longevity of battery systems, accurate estimation of the State of Health (SOH) of lithium-ion batteries is essential. As an internal state variable, SOH is difficult to measure directly with sensors and is therefore often estimated through indirect methods. The accuracy of SOH estimation largely depends on the quality of the extracted health features that are correlated with battery aging. This review systematically analyzes and evaluates mainstream feature extraction methodologies for lithium-ion battery SOH estimation. It clarifies the link between macroscopic aging phenomena (capacity fade and impedance rise) and microscopic electrochemical degradation mechanisms, such as loss of active material (LAM) and loss of lithium inventory (LLI). A comprehensive survey is conducted on five primary feature categories: (1) Voltage-current curve features, derived from standard charging protocols (e.g., Constant Current-Constant Voltage, CC-CV), including temporal indicators and capacity metrics within specific voltage windows. (2) Differential curve features, such as Incremental Capacity Analysis (ICA) and Differential Voltage Analysis (DVA), identifying electrochemical phase transitions whose peak attributes (height, position, area) serve as health indicators. (3) Pulse power characterization features, obtained from Hybrid Pulse Power Characterization (HPPC) tests, reflecting DC internal resistance (DCR) and variations in the open-circuit voltage (OCV) versus state of charge (SOC) curve. (4) Electrochemical impedance spectroscopy (EIS) features, extracted from raw impedance data, including parameters fitted using equivalent circuit models (ECM) and deconvolution results from distribution of relaxation times (DRT) analysis. (5) Multi-physics field features, which utilize non-electrical signals from thermal, ultrasonic, and mechanical sensors, providing additional diagnostic dimensions. Publicly available datasets (e.g., NASA, CALCE, Oxford) are also reviewed as benchmarks. The analysis finds that voltage-current curve features are computationally efficient but typically require full charging cycles. While ICA/DVA offer deep mechanistic insight by linking peak changes to LAM and LLI, their susceptibility to noise and current rate complicates online implementation. HPPC-derived features effectively track impedance growth but require accurate OCV correction. EIS provides the most comprehensive diagnostic information, with ECM offering physically meaningful parameters and DRT excelling at decoupling overlapping processes, though measurements are time-intensive. Multi-physics features capture structural and thermal degradation, offering complementary perspectives. A key finding is that no single feature can reliably provide robust and high-precision SOH estimation under complex and variable real-world conditions. Given the limitations of single features, future research is expected to focus on: (1) establishing standardized public benchmarks and evaluation protocols to enable objective comparison and accelerate technological progress; (2) fusing multi-physics features (electrical, thermal, mechanical) to develop more comprehensive and robust health indicators; and (3) integrating physical models with data-driven methods, such as physics-informed neural networks (PINNs), to enhance model interpretability, data efficiency, and generalization.

       

    /

    返回文章
    返回