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    藻类生物质衍生功能性碳材料的制备与应用研究进展

    Advances in Preparation and Applications of Algal-Derived Functional Carbon Materials

    • 摘要: 面对日益严峻的环境污染与能源危机,开发以绿色可再生生物质为碳源的功能性碳材料,是实现“双碳”目标与可持续发展的关键路径。藻类生物质作为第三代生物质资源,兼具不占用耕地、生长周期短、单位产量高、可修复水体富营养化及天然富含杂原子的优势,无需额外添加掺杂剂即可实现碳材料杂原子原位掺杂,为功能性碳材料制备提供了理想前驱体。本文系统综述了藻类生物质衍生功能性碳材料的研究进展。首先,分析了藻类生物质原料特性,梳理不同藻类的工业分析、元素分析及成分组成数据,明确其作为碳源的潜力。随后,阐述了制备工艺,涵盖热解碳化、水热碳化、微波碳化3种基础碳化方法,并对比各工艺参数对产物性能的影响。同时,介绍了物理活化、化学活化、金属盐/氧化物修饰3类活化改性技术,阐述其在优化碳材料孔隙结构与表面官能团方面的作用。整理了藻类生物炭在吸附、储能、催化3大领域的应用研究。最后,总结了当前研究面临的挑战,包括藻类收集成本高、成分稳定性差,碳材料结构调控难度大、部分性能不及商用碳材料及规模化工艺不成熟等问题,为后续理论研究与产业化应用提供参考。

       

      Abstract: Amidst growing concerns over global environmental pollution and fossil fuel depletion, developing functional carbon materials from green and renewable biomass is a promising strategy that aligns with carbon peaking and carbon neutrality goals, as well as the principles of sustainable development. Among various biomass resources, algal biomass, regarded as a highly promising third-generation feedstock, offers unique advantages. It does not occupy arable land or compete with food crops, and its short growth cycle enables rapid proliferation, resulting in a yield per unit area significantly higher than that of traditional biomass. Additionally, algae can effectively absorb nutrients such as nitrogen and phosphorus from water during growth, thus contributing to the mitigation of eutrophication. Moreover, algae are inherently enriched with heteroatoms such as nitrogen and oxygen, allowing for in-situ heteroatom doping during carbon material synthesis without the need for additional dopants. This inherent compositional advantage makes algal biomass an excellent precursor for preparing functional carbon materials. This review systematically summarizes the research progress on functional carbon materials derived from algal biomass. First, it provides an in-depth analysis of the raw material characteristics of various algal types, including proximate analysis, elemental composition, and specific component data, thereby highlighting their potential as high-quality carbon sources. Subsequently, the review elaborates on relevant preparation methods, encompassing three fundamental carbonization techniques: pyrolytic carbonization, hydrothermal carbonization, and microwave carbonization. It also compares the effects of key processing parameters on the performance of the resulting carbon materials. Furthermore, it thoroughly discusses three commonly used activation and modification strategies—namely, physical activation, chemical activation, and metal salt/oxide modification—and their roles in optimizing pore structures and tailoring surface functional groups. The review also highlights the applications of algal biochar in three key areas: adsorption, energy storage, and catalysis, demonstrating its diverse application potential. Finally, it summarizes the critical bottlenecks in current research, including high algae collection costs, batch-to-batch compositional inconsistency, difficulties in fine-tuning microstructures, performance gaps with commercial alternatives, and the absence of mature large-scale production technologies. This review provides valuable insights and serves as a comprehensive reference for future theoretical studies and industrial applications.

       

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