Abstract:minum sulfate (Al2(SO4)3·18H2O),tetrapropyl ammonium hydroxide (TPAOH) and NaOH as rawmaterials. The products were characterized by X-ray diffraction (XRD),infrared spectrometer (IR)and scanning electron microscope (SEM). The treatment effect of ZSM-5 zeolite/glass fiber compositeon copper - containing wastewater was investigated. The results showed that when the dosage ofcomposite material was 0.8 g,the crystallization time was 48 h,the crystallization temperature was 180℃ and the concentration of adsorption solution was 10 mg/L,the adsorption rate of ZSM-5/untreatedglass fiber reached 83.9% after 300 min,and the adsorption rate of ZSM-5/glass fiber pretreated byNaOH reached 89.5% after 420 min. Close-