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Performance determination and evaluation of SCR denitration catalystin a high-arsenic coal-fired power plant

Received Date:2021-12-26

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    Abstract:In order to analyze the effect of plate-type anti-arsenic-poisoning SCR denitration catalystson treating high-arsenic co... Open+
    Abstract: In order to analyze the effect of plate-type anti-arsenic-poisoning SCR denitration catalystson treating high-arsenic coal-fired flue gas of coal-fired power plant,the denitrification activities ofanti-arsenic-poisoning SCR denitration catalyst and fresh catalyst were tested. The catalyst sampleswere characterized by X-ray fluorescence ( XRF) ,N2 adsorption /desorption,X-ray diffraction( XRD)and X-ray photoelectron spectroscopy ( XPS) . The results showed that the denitrification activity of theone-year-used catalyst under 150~450 ℃ was close to that of the fresh catalyst. After one year of op-eration,the content of arsenic in the catalyst reached 3.06%,mainly in the form of As2O5. The specificsurface area of the catalyst decreased slightly. The crystal form of the support TiO2 and the content ofV4+ and Oα did not change significantly. The catalyst had no obvious physical and chemical arsenic poi-soning,showing good anti-arsenic poisoning performance. Close-

    Authors:

    • REN Cuitao1
    • CHEN Chen2
    • LIU Dingjia2
    • JIA Haiwei2
    • QU Yanchao2

    Units

    • 1.Beijing National Power Group Co.,Ltd.,Beijing 102206,China
    • 2.Zhejiang Kezhuo Environmental Protection Technology Co.,Ltd.,Shaoxing 312300,China

    Keywords

    • SCR catalyst
    • Antiarsenicpoisoning
    • Denitrification performance
    • Higharsenic flue gas

    Citation

    REN Cuitao,CHEN Chen,LIU Dingjia,et al. Performance determination and evaluation of SCR denitration catalystin a high-arsenic coal-fired power plant[J]. Energy Environmental Protection,2022,36( 2) : 90-95.
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