Research progress on synthesis of butyl mercaptan from hydrogen sulfideas sulfur source
Received Date:2021-09-14
Abstract:Based on the domestic and foreign literature on the synthesis of butyl mercaptan using hydro-gen sulfide as a sulfur sou... Open+
Abstract: Based on the domestic and foreign literature on the synthesis of butyl mercaptan using hydro-gen sulfide as a sulfur source,the characteristics of various methods were discussed,especially the olefinvulcanization method. The catalytic behaviors of Lewis acid catalysts,zeolite catalysts,ion exchangeresin catalysts,and transition metal salt-modified aluminum-based catalysts were expounded. The anal-ysis suggests that the transition metal salt-modified aluminum-based catalyst can stabilize the activephase in the metastable state and has high catalytic activity,because of the strong interaction betweenthe carrier and active metal. In order to remove hydrogen sulfide and obtain economic benefits,the sul-fur source can be hydrogen sulfide in reducing flue gas and the carbon source can be low-carbon olefinsproduced in the process of petroleum catalytic cracking and olefins preparation from methanol. Close-
Authors:
- LI Yubei1,2,3
- LU Jichang1,2,3
- FANG Jian1,2,3
- FENG Siyou1,2,3
- HE Bihui1,2,3
- LUO Yongming1,2,3
Units
- 1.Faculty of Environmental Science and Engineering,Kunming University of Science and Technology,Kunming 650500,China,
- 2.The Innovation Team for Volatile Organic Compounds Pollutants Control and ResourceUtilization of Yunnan Province,Kunming 650500,China,
- 3.The Higher Educational Key Laboratory forOdorous Volatile Organic Compounds Pollutants Control of Yunnan Province,Kunming 650500,China
Keywords
- Butyl mercaptan
- Hydrogen sulfide
- Resource utilization
- Catalyst
Citation
LI Yubei,LU Jichang,FANG Jian,et al. Research progress on synthesis of butyl mercaptan from hydrogen sulfideas sulfur source[J]. Energy Environmental Protection,2022,36( 2) : 22-28.
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