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Research progress of low-temperature NH3-SCR catalysts and denitration mechanism

Received Date:2021-07-03

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    Abstract:In order to develop low-temperature NH3 selective catalytic reduction (NH3-SCR) catalysts with high activity and high re... Open+
    Abstract:

    In order to develop low-temperature NH3 selective catalytic reduction (NH3-SCR) catalysts with high activity and high resistance, the research regarding the denitration activity, sulfur and water resistance of four main low-temperature denitration catalysts (precious metals, molecular sieves, carbon-based materials and transition metal oxides) were introduced. In addition, the low-temperature denitration technologies based on in-situ diffuse reflectance infrared Fourier transform spectroscopy and density functional theory were introduced. It is concluded that the NH3-SCR catalysts composed of one or more metal materials generally have good low-temperature activity, but its sulfur and water resistance need further improvement. The surface acidity and the number of active sites exposed are closely related to the sulfur and water resistance of catalysts. Denitration mechanism is helpful to analyze the influence of SO2 and steam on the denitration process.

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    Authors:

    • JIANG Jin1,2
    • XIA Yongjun1
    • HU Jia1
    • GUO Lina2
    • JIA Yong2,*

    Units

    • 1.Anhui Xinchuang Energy Saving & Environmental Protection Science & Technology Co., Ltd., Ma Anshan 243071, China,
    • 2.School of Energy and Environment, Anhui University of Technology, Ma Anshan 243002, China

    Keywords

    • Low temperature denitration
    • NH3 SCR
    • Catalyst
    • In situ diffuse reflectance infrared Fourier transform spectroscopy
    • Density functional theory

    Citation

    JIANG Jin, XIA Yongjun, HU Jia, et al. Research progress of low-temperature NH3-SCR catalysts and denitration mechanism[J]. Energy Environmental Protection, 2021, 35(5): 7-15.

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